Some features of WorldCat will not be available. A novel 3D 1HNC heteronuclear correlation experiment was used for the amide proton resonance assignment. The main focus of this thesis is the development of a strategy for the collection of a large number of distance restraints for structure determination. Structural studies by solid state NMR on the function of nanoscale materials: The 13CC long-range correlations obtained with the PDSD recoupling method were converted into distance restraints using an empirical approach.
Synthesis of this catalytic system is accomplished by chemical vapor deposition onto the support. Preview this item Preview this item. Home About Help Search. These issues are no longer insurmountable hurdles that once deemed solid-state NMR a rather exotic method for structure determination. The unique virtue of solid- state NMR lies in its ability to study biomolecules without size restrictions and without the need of large well-ordered crystals.
Please re-enter recipient e-mail address es. The study of nmf membrane proteins within structural genomics projects is an obvious next application of the novel technique described herein, together with the study of receptor-bound agonists and antagonists.
The dissertatioon site-directed 13C-enriched samples needed for the measurement of long-range constraints were obtained by growing bacteria on [C] glycerol and [1,C] glycerol. Hochschulschrift Additional Physical Format: The name field is required.
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A simple method was derived to extract distance information from build-up curves of cross-peak intensities in 15NN PDSD spectra. Structure determination of immobilized proteins by solid-state NMR spectroscopy Festiörper dc. WorldCat is fesykörper world’s largest library catalog, helping you find library materials online. Please verify that you are not a robot.
In the second part of this work the effect of rather different interfacial interactions are examined, namely those of structural changes following surface treatments on the optical properties of nanoscale Group III-V semiconductors and their ternary analogs.
In this work two examples in nanomaterials and interfacial chemistry are described where critical atomic level structural details, as well as information on dynamics, were obtained by the use of solid state NMR spectroscopy in conjunction with computational and related experimental approaches.
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Finding libraries that hold fesykörper item Joren Sebastian Retel Publisher: Reviews User-contributed reviews Add a review and share your thoughts with other readers.
Citations are based on reference standards. Advanced Search Find a Library. In particular, shift differences provided insight into contacts between SH3 molecules in the micro-crystalline preparation used.
Refubium – Structure determination of immobilized proteins by solid-state NMR spectroscopy
Joren Sebastian Retel Find more information about: Linked Data More info about Linked Data. Festkör;er a copy online Links to this item Volltext Volltext Volltext kostenfrei. Please enter the message. Chapter 4 describes how we determined the labelling pattern of the two biosynthetically site-directed 13C-enriched samples, using several solution NMR experiments.
You may send this item to up to five recipients. This thesis demonstrates the forthcoming role of solid-state MAS NMR as a mainstream technique for structural investigation of fextkörper, as a method complementary to solution NMR and single-crystal diffraction. Please select Ok if you would like to proceed with this request anyway.
The main focus of this thesis is the development of a strategy for the collection of a large number of distance restraints for structure determination. Your rating has been recorded. The spectroscopic technique we chose for the collection of structural-defining 13CC distances is the proton-driven spin diffusion PDSD recoupling fsstkörper. Remember me on this computer. Structure determination of immobilized proteins by solid-state NMR spectroscopy.
A structure was derived from solid-state data only, with a backbone root-mean square-deviation of 0. Would you also like to submit a review for this item?